Chemical Oxygen Demand (COD) is a test that measures the amount of oxygen required to chemically oxidize the organic material and inorganic nutrients, such as Ammonia or Nitrate, present in water.
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What is the difference between biological oxygen demand and Chemical Oxygen Demand?
Biochemical oxygen demand (BOD) is the amount of oxygen required by the microorganisms to break down the organic materials, whereas chemical oxygen demand (COD) is the amount of oxygen required to break down the organic material via oxidation.
What is Chemical Oxygen Demand and Biochemical Oxygen Demand of water?
The decay of organic matter in water is measured as biochemical or chemical oxygen demand. Oxygen demand is a measure of the amount of oxidizable substances in a water sample that can lower DO concentrations.
Which is better COD or BOD?
COD is normally higher than BOD because more organic compounds can be chemically oxidised than biologically oxidised. This includes chemicals toxic to biological life, which can make COD tests very useful when testing industrial sewage as they will not be captured by BOD testing.
What is importance of determining COD & BOD?
COD and BOD tests are important because they help in the determination of the amount of waste in wastewater. This is important because the organic content in wastewater needs to be reduced before the wastewater is discharged.
Why COD is more than BOD?
The COD test uses a chemical (potassium dichromate in a 50% sulfuric acid solution) that “oxidizes” both organic (predominate) and inorganic substances in a wastewater sample, which results in a higher COD concentration than BOD concentration for the same wastewater sample since only organic compounds are consumed …
What is COD and its importance?
Chemical oxygen demand (COD) is the amount of dissolved oxygen that must be present in water to oxidize chemical organic materials, like petroleum. COD is used to gauge the short-term impact wastewater effluents will have on the oxygen levels of receiving waters.
What is COD in simple words?
COD is the oxygen demand that is consumed by both inorganic and organic matter present in the wastewater sample. The chemical oxygen demand is expressed as the mass of oxygen consumed over the volume of the solution. Its SI unit is milligrams per liter (mg/l).
Why COD is measured?
COD is an indicative measure of the amount of oxygen that can be consumed by reactions in a measured solution. It is commonly expressed in mass of oxygen consumed over volume of solution, which in SI units is milligrams per liter (mg/L). A COD test can be used to easily quantify the amount of organics in water.
What is BOD value of water?
BOD values range widely; generally, pristine waters have a value below 1 mg l−1, moderately polluted waters 2–8 mg l−1, and treated municipal sewage 20 mg l−1. Standards for the discharge of effluent from WWTPs have the range 20–30 mg l−1 and require a minimum flow in receiving waters to ensure sufficient dilution.
What is the difference between biochemical and Biological Oxygen Demand?
Biochemical oxygen demand (BOD, also called biological oxygen demand) is the amount of dissolved oxygen needed (i.e., demanded) by aerobic biological organisms to break down organic material present in a given water sample at certain temperature over a specific time period (Kaiser, 1998).
What is the importance of BOD?
Importance of BOD It indicates the amount of organic pollution present in an aquatic ecosystem. It determines the amount of organic matter present in soils, sewages, sediment, garbage, sludge, etc. The biochemical oxygen demand also determines the rate of respiration in living beings.
Why is BOD measured for 5 days?
BOD occurs in 2 general stages. While calculating the oxygen demand, the carbonaceous stage is taken into account. This stage is almost completed in 5 days, which means that most of the organic content of the sewage is oxidized under aerobic conditions in 5 days. Hence ,BOD for 5 days is calculated.
Who limits COD in water?
According to standards of Central Pollution Control Board, permissible value of BOD is 30 mg/l and COD is 250 mg/l.
What happens if COD is high?
Higher COD levels mean a greater amount of oxidizable organic material in the sample, which will reduce dissolved oxygen (DO) levels. A reduction in DO can lead to anaerobic conditions, which is deleterious to higher aquatic life forms.
What happens if BOD is low?
Inversely, low BOD means less oxygen is being removed from water, so water is generally purer. Cold water retains oxygen better than warmer water, so in summer months, dissolved oxygen is usually lower from the start.
How COD is calculated?
There is a formula for calculating COD. Consider the formula for COD calculation: (a – b) X C X 8,000 / the volume of the sample in mL. Let “a” represent the titrant used for your sample expressed in mL. Let “b” represent the titrant used for your blank sample in mL.
What is the principle of COD?
The principle behind the COD testing method is that, under acidic conditions, a strong oxidising agent will oxidise almost any organic compound to carbon dioxide. COD analysis will measure the equivalent amount of oxygen that is required to chemically oxidise organic compounds in water.
What is the limit of COD?
The chemical oxygen demand (COD) concentration in a treated effluent, if observed to be persistently greater than 250 mg/l before disposal to any receiving body (public sewer, land for irrigation, inland surface water and marine coastal areas), such industrial units are required to identify chemicals causing the same.
Why COD testing is important?
The COD test is often used to monitor water treatment plant efficiency. This test is based on the fact that a strong oxidizing agent, under acidic conditions, can fully oxidize almost any organic compound to carbon dioxide.
What are the sources of COD?
Sources of COD in stormwater are varied. However, soluble organic compounds are most likely to contribute to escalated COD concentrations. Residual food waste from bottles and cans, antifreeze, emulsified oils are all high in COD and are common sources of COD for industrial stormwater.
What is the value of COD?
The COD value indicates the amount of oxygen which is needed for the oxidation of all organic substances in water in mg/l or g/m3. The COD (Chemical Oxygen Demand) is closely related to the laboratory standard method named Dichromate-Method.
Why Sulphuric acid is used in COD?
Chemical Oxygen Demand (COD) 1% Silver Sulphate in Sulphuric Acid (conc.) provides the primary and secondary digestion catalysts for oxidation of carbon during chemical oxidation.
In which water BOD is maximum?
Notes: BOD is amount of dissolved oxygen needed by aerobic biological organisms in a body of water to break down organic material present in a given water sample at certain temperature over a specific time period, for running rivers, it would be minimum and for Untreated Municipal waste water it would be maximum.
Does BOD depend on temperature?
The BOD removal rate in the bioreactor increased when the temperature increased from 20 degrees C to 30 degrees C, 40 degrees C, and 50 degrees C, but it decreased when the temperature increased from 50 degrees C to 60 degrees C. Higher temperature enhanced the endogenous respiration of microbes in the bioreactor.